Abstract
Photothermal phase change materials (PCMs) are emerging as one kind of multifunctional wearable energy materials that integrate latent-heat storage with solar-to-thermal conversion, electrothermal heating, radiative regulation, and intelligent sensing. Unlike conventional PCMs, wearable photothermal PCMs should simultaneously satisfy thermal performance, flexibility, breathability, leakage resistance, cycling stability, and skin compatibility. We summarize recent progress in photothermal PCMs for wearable thermal management and intelligent healthcare, focusing on material systems, energy-conversion mechanisms, and application scenarios. Shape-stabilized solid-liquid composites, intrinsically flexible solid-solid/polymeric PCMs, photothermal-filler-enhanced composites, and PC-Azo molecular solar thermal systems are discussed. Their applications in personal thermal management, solar-thermal/optically switched heat release, wearable thermotherapy, intelligent healthcare, wearable electronics, and self-powered systems are highlighted. Finally, key challenges and future opportunities are proposed, including human-centered evaluation standards, multimodal thermal regulation, epidermal phase-change hydrogels, phase-change solar thermal textiles, and AI-guided material design.
Keywords
References
-
1. Shi J, Qin M, Aftab W, Zou R. Flexible phase change materials for thermal energy storage. Energy Storage Mater. 2021;41:321-342.[DOI]
-
2. Zhao X, Zou D, Wang S. Flexible phase change materials: Preparation, properties and application. Chem Eng J. 2022;431:134231.[DOI]
-
3. Chen M, Liu Y, Zhao X. Emerging passive thermoregulatory textiles through tailoring different heat transfer routes. Text Res J. 2023;93(13-14):3414-3439.[DOI]
-
4. Liu X, Zhang M, Hou Y, Pan Y, Liu C, Shen C. Hierarchically superhydrophobic stereo-complex poly (lactic acid) aerogel for daytime radiative cooling. Adv Funct Mater. 2022;32(46):2207414.[DOI]
-
6. Peng Y, Li W, Liu B, Jin W, Schaadt J, Tang J, et al. Integrated cooling (i-Cool) textile of heat conduction and sweat transportation for personal perspiration management. Nat Commun. 2021;12:6122.[DOI]
-
7. Han W, Tan J, Zhu H, Wu T, Wang C. Tunable dual-driven photothermal/electrothermal textile heater for personal thermal management. Compos Part A Appl Sci Manuf. 2026;203:109583.[DOI]
-
9. Lu L, Guo H, Martin-Fabiani I, Zhou Y, Willcock H, Vladisavljević GT, et al. Recent advances and applications of flexible phase change composites. EcoMat. 2025;7(4):e70004.[DOI]
-
10. Mohtasim MS, Das BK. MXene based composite phase change materials for thermal energy storage applications: Featuring bio-mimic approaches. Renew Sustain Energy Rev. 2025;207:114952.[DOI]
-
11. Peng L, Su B, Yu A, Jiang X. Review of clothing for thermal management with advanced materials. Cellulose. 2019;26(11):6415-6448.[DOI]
-
12. Zhang X, Chao X, Lou L, Fan J, Chen Q, Li B, et al. Personal thermal management by thermally conductive composites: A review. Compos Commun. 2021;23:100595.[DOI]
-
13. Kou Y, Sun K, Luo J, Zhou F, Huang H, Wu ZS, et al. An intrinsically flexible phase change film for wearable thermal managements. Energy Storage Mater. 2021;34:508-514.[DOI]
-
14. Xu F, Zhang T, Xu Z, Zhao Y. Solid-solid phase change fibers with enhanced energy storage density for temperature management. J Energy Storage. 2024;79:110190.[DOI]
-
15. Liang C, Zhang W, Liu C, He J, Xiang Y, Han M, et al. Multifunctional phase change textiles with electromagnetic interference shielding and multiple thermal response characteristics. Chem Eng J. 2023;471:144500.[DOI]
-
16. Yin GZ, Hobson J, Duan Y, Wang DY. Polyrotaxane: New generation of sustainable, ultra-flexible, form-stable and smart phase change materials. Energy Storage Mater. 2021;40:347-357.[DOI]
-
18. Ding J, Chen S, Zhao Y, Wu X, Zhao S, Yuan A, et al. Engineering polymeric phase-change sub-microcapsules with a high encapsulation fraction by facile, versatile suspension polymerization. ACS Sustainable Chem Eng. 2023;11(38):14000-14009.[DOI]
-
19. Gu B, Dai Z, Pan H, Zhao D. Integration of prolonged phase-change thermal storage material and radiative cooling textile for personal thermal management. Chem Eng J. 2024;493:152637.[DOI]
-
20. Yu Z, Wang F, He W, Wang Y, Dai B, Zhang X. Phase-change material-integrated dual-mode thermal management Janus films with enhanced radiative cooling and solar heating. ACS Appl Polym Mater. 2025;7(6):3555-3563.[DOI]
-
21. Li Y, Li Y, Lu T, Xiang Y, Cai T, Tan G, et al. Phase change material-integrated Janus fabric with radiative cooling/solar heating for adaptive thermal management. Sol Energy Mater Sol Cells. 2026;297:114134.[DOI]
-
22. Wang J, Yue H, Du Z, Cheng X, Wang H, Du X. Highly flexible phase-change film with solar thermal storage and sensitive motion detection for wearable thermal management. Chem Eng J. 2023;466:143334.[DOI]
-
23. Li D, Tang Y, Zuo X, Zhao X, Shang K, Yang H. Functionally constructed mineral microspheres for efficient photothermal conversion and thermal energy storage. Carbon. 2022;196:365-377.[DOI]
-
24. Zhao J, Zhou J, Li H, Xiao A. Ti3C2Tx MXene and cellulose-based aerogel phase change composite decorated laminated fabric with excellent electro/solar-thermal conversion and high latent heat. Carbohydr Polym. 2023;316:121031.[DOI]
-
25. Gao Y, Chen X, Jin X, Zhang C, Zhang X, Liu X, et al. Multifunction integration within magnetic CNT-bridged MXene/CoNi based phase change materials. EScience. 2024;4(6):100292.[DOI]
-
26. Li Y, Li P, Yu H, Diao X, Liu P, Zhao Z, et al. Photoelectric dual-mode triggered phase change materials for all-weather personal thermal management and shape memory. J Colloid Interface Sci. 2024;665:1007-1016.[DOI]
-
27. Zhu X, Liu J, Zhang L, Zhao W, Cao Y, Liu X. Dual-mode MXene-based phase-change composite towards enhanced photothermal utilization and excellent infrared stealth. Small. 2024;20(48):2405694.[DOI]
-
28. Chen X, Gao H, Hai G, Jia D, Xing L, Chen S, et al. Carbon nanotube bundles assembled flexible hierarchical framework based phase change material composites for thermal energy harvesting and thermotherapy. Energy Storage Mater. 2020;26:129-137.[DOI]
-
30. Zhang Q, Xue T, Tian J, Yang Y, Fan W, Liu T. Polyimide/boron nitride composite aerogel fiber-based phase-changeable textile for intelligent personal thermoregulation. Compos Sci Technol. 2022;226:109541.[DOI]
-
31. Jung Y, Kim M, Kim T, Ahn J, Lee J, Ko SH. Functional materials and innovative strategies for wearable thermal management applications. Nano Micro Lett. 2023;15(1):160.[DOI]
-
32. Ju YS. Thermal management and control of wearable devices. iScience. 2022;25(7):104587.[DOI]
-
34. Huang ZJ, Liu YL, Zhu TY, Jiang WJ, Sun DX, Yang JH, et al. Phase change hydrogels with tunable adhesion for wearable thermal management and intelligent healthcare. J Energy Storage. 2024;98:113043.[DOI]
-
35. Zhou YC, Yang J, Li WD, Yu P, Zhang ZM, Bai L, et al. Highly stretchable phase change composites for simultaneous health monitoring and thermotherapy. Chem Eng J. 2023;470:144175.[DOI]
-
36. Li Y, Chen X. Wearable thermotherapy devices made with phase change modules. Device. 2024;2(2):100282.[DOI]
-
37. Nie S, Cai M, Yang H, Shen L, Wang S, Zhu Y, et al. Soft, stretchable thermal protective substrates for wearable electronics. npj Flex Electronics. 2022;6:36.[DOI]
-
40. Liu H, Tang J, Dong L, Wang H, Xu T, Gao W, et al. Optically triggered synchronous heat release of phase-change enthalpy and photo-thermal energy in phase-change materials at low temperatures. Adv Funct Mater. 2021;31(6):2008496.[DOI]
-
42. Gao J, Feng Y, Fang W, Wang H, Ge J, Yang X, et al. Co-harvest phase-change enthalpy and isomerization energy for high-energy heat output by controlling crystallization of alkyl-grafted azobenzene molecules. Energy Environ Mater. 2024;7(3):e12607.[DOI]
-
43. Wu MQ, Wu S, Cai YF, Wang RZ, Li TX. Form-stable phase change composites: Preparation, performance, and applications for thermal energy conversion, storage and management. Energy Storage Mater. 2021;42:380-417.[DOI]
-
44. Liang R, Yuan B, Zhang F, Feng W. Azopyridine polymers in organic phase change materials for high energy density photothermal storage and controlled release. Angew Chem Int Ed. 2025;64(7):e202419165.[DOI]
-
45. Jiang Z, Zhang F, Feng W. Percolating MXene networks and LDH thermal bridges in 3D hierarchical polyimide aerogels for rapid thermal charging, leakage-resistant solar–thermal phase-change storage. Small. 2026;22(9):e13143.[DOI]
-
46. Sharma A, Tyagi VV, Chen CR, Buddhi D. Review on thermal energy storage with phase change materials and applications. Renew Sustain Energy Rev. 2009;13(2):318-345.[DOI]
-
47. Królikowski M, Więckowski M, Żółtańska K, Królikowska M. Eutectic phase change materials based on novel dicationic isoquinoliunium ionic liquids: Synthesis and characterization. J Chem Eng Data. 2024;69(3):958-972.[DOI]
-
48. Wu MQ, Wu S, Cai YF, Wang RZ, Li TX. Form-stable phase change composites: Preparation, performance, and applications for thermal energy conversion, storage and management. Energy Storage Mater. 2021;42:380-417.[DOI]
-
49. Zhang J, Zhang Y, Wu S, Ji Y, Mao Z, Wang D, et al. Weavable coaxial phase change fibers concentrating thermal energy storage, photothermal conversion and thermochromic responsiveness toward smart thermoregulatory textiles. Chem Eng J. 2024;483:149281.[DOI]
-
50. Zhang X, Sun K, Liu H, Chen J, Yan X, Kou Y, et al. Flexible insulating phase change composite film with improved thermal conductivity for wearable thermal management. Nano Energy. 2024;121:109256.[DOI]
-
53. Wang C, Dong H, Cheng C, Sun K, Jin T, Shi Q. Flexible and biocompatible silk fiber-based composite phase change material for personal thermal management. ACS Sustainable Chem Eng. 2022;10(49):16368-16376.[DOI]
-
54. Deng G, Yang Y, Lu S, Ma L, Wu G. Silk fabrics modified with photothermal phase change microcapsules for personal thermal management. IJN. 2024;19:8485-8499.[DOI]
-
55. Fu L, Yang J, Dong L, Yu H, Yan Q, Zhao F, et al. Solar thermal storage and room-temperature fast release using a uniform flexible azobenzene-grafted polynorborene film enhanced by stretching. Macromolecules. 2019;52(11):4222-4231.[DOI]
-
56. Liu H, Feng Y, Feng W. Alkyl-grafted azobenzene molecules for photo-induced heat storage and release via integration function of phase change and photoisomerization. Compos Commun. 2020;21:100402.[DOI]
-
57. Li L, Peng J, Wang L, Lai J, Zhao C, Xiang D, et al. Highly flexible GO-polyurethane solid-solid phase change composite materials for efficient photothermal conversion and thermal energy storage. J. Mater. Che. A. 2025;13(4):3073-3083.
-
58. Yu H, Guo P, Qin M, Han G, Chen L, Feng Y, et al. Highly thermally conductive polymer composite enhanced by two-level adjustable boron nitride network with leaf venation structure. Compos Sci Technol. 2022;222:109406.[DOI]
-
60. Sun Y, Zhang F, Guo L, Zhu Z, Gao X, Feng W, et al. Thermally conductive nanocomposite with silicon carbide nanowire-bridged boron nitride skeleton for multifunctional thermal interface materials. Compos Part A Appl Sci Manuf. 2025;192:108775.[DOI]
-
61. Luo T, Kong L, Li L, Lu J, Yu Z, Lin B, et al. A flexible wearable phase change composite with electro-/ photo-thermal heating for personal thermal management and human body motion detection. Chem Eng J. 2024;486:150443.[DOI]
-
62. Li J, Chang Q, Xue C, Yang J, Hu S. Carbon dots efficiently enhance photothermal conversion and storage of organic phase change materials through interfacial interaction. Carbon. 2023;203:21-28.[DOI]
-
63. Sun Z, Shi T, Wang Y, Li J, Liu H, Wang X. Hierarchical microencapsulation of phase change material with carbon-nanotubes/polydopamine/silica shell for synergistic enhancement of solar photothermal conversion and storage. Sol Energy Mater Sol Cells. 2022;236:111539.[DOI]
-
64. Wang L, Yu H, Feng W. Photothermal phase change energy storage materials: A groundbreaking new energy solution. Research. 2024;7:460.[DOI]
-
66. Xu X, Feng J, Li WY, Wang G, Feng W, Yu H. Azobenzene-containing polymer for solar thermal energy storage and release: Advances, challenges, and opportunities. Prog Polym Sci. 2024;149:101782.[DOI]
-
67. Wang K, Yu H, Gao J, Feng Y, Feng W. Optimizing the performance of phase-change azobenzene: From trial and error to machine learning. J Mater Chem C. 2024;12(11):3811-3837.[DOI]
-
68. Jiang Y, Liu J, Luo W, Quan X, Li H, Huang J, et al. High-energy and light-actuated phase change composite for solar energy storage and heat release. Surf Interfaces. 2021;24:101071.[DOI]
-
70. Wang H, Feng Y, Yu H, Dong L, Zhai F, Tang J, et al. Utilisation of photo-thermal energy and bond enthalpy based on optically triggered formation and dissociation of coordination bonds. Nano Energy. 2021;89:106401.[DOI]
-
71. Niu C, Li M, Pan G, Lu J, Yu H, Ge X, et al. Sandwich-structured porous foam from sodium alginate-intercalated MXene/polyethylene glycol: Photothermal conversion, phase change storage and electromagnetic interference shielding. Carbohydr Polym. 2026;381:125143.[DOI]
-
72. Wang L, Zhao F, Yu H, Xia R, Jiang Z, Feng W. Graphene oxide-molten salt composite material for high-temperature photothermal phase change energy storage. Adv Funct Mater. 2026;36(46):e75374.[DOI]
-
73. Wu Y, Dong L, Tang S, Liu X, Han Y, Zhang S, et al. An innovative azobenzene-based photothermal fabric with excellent heat release performance for wearable thermal management device. Small. 2024;20(49):2404310.[DOI]
-
74. Hu J, Huang S, Yu M, Yu H. Flexible solar thermal fuel devices: Composites of fabric and a photoliquefiable azobenzene derivative. Adv Energy Mater. 2019;9(37):1901363.[DOI]
-
76. Xu X, Xing Y, Yin Y, Fang W, Wu B, Bei P, et al. Flexible wearable fabrics for solar thermal energy storage and release in on-demand environments. Chem Eng J. 2023;466:143175.[DOI]
-
77. Zhang Z, Fei L, Tan J, Yu W, Zhang C, Wang C. Azobenzene-based solar thermal elastic fiber with efficient energy storage for personal thermal management. Sol Energy Mater Sol Cells. 2025;293:113886.[DOI]
-
78. Zhang Y, Dong L, Pan H, Zhou M, Zhai F, Ye Z, et al. Directly sunlight-chargeable core-shell azobenzene fabric via coaxial electrospinning with tunable personal thermal management. Energy Environ Mater. 2026;e70436.[DOI]
-
79. Axelrod YK, Diringer MN. Temperature management in acute neurologic disorders. Neurol Clin. 2008;26(2):585-603.[DOI]
-
80. Brown DJA, Brugger H, Boyd J, Paal P. Accidental hypothermia. N Engl J Med. 2012;367(20):1930-1938.[DOI]
-
81. Zhao JQ, Wang X, Wang XR, Zhao HW, Lu MN, Xu WQ, et al. Phase change thermal interface film with bicontinuous and textured filler network for efficient wearable heat dissipation. Chem Eng J. 2024;500:156922.[DOI]
-
82. Faruk MO, Ahmed A, Jalil MA, Islam MT, Shamim AM, Adak B, et al. Functional textiles and composite based wearable thermal devices for Joule heating: Progress and perspectives. Appl Mater Today. 2021;23:101025.[DOI]
-
83. Wang H, Yu Y, Yang X, Wang S, Ge J, Yang Q, et al. A smart mechanical-energy harvesting and self-heating textile device for photo-thermal energy utilization. EcoMat. 2023;5(5):e12337.[DOI]
-
87. Peng Y, Dong J, Gu Y, Zhang Y, Long J, Park S, et al. Smart temperature-adaptive thermal regulation textiles integrating passive radiative cooling and reversible heat storage. Nano Energy. 2024;131:110311.[DOI]
-
88. Duran M, Serrano A, Dauvergne JL, Nikulin A, Labidi J, Palomo del Barrio E. High performance and durable PCM/polymer fibers by reliable microfluidic encapsulation. J Energy Storage. 2025;132:117916.[DOI]
-
89. Zheng C, Jiang P, Rui C, Zhang X, Qu L, Fan T, et al. Graphene and MXene fibers: Rising stars for emerging smart textiles. Soft Sci. 2026;6(2):
-
90. Fei L, Yin Y, Yang M, Zhang S, Wang C. Wearable solar energy management based on visible solar thermal energy storage for full solar spectrum utilization. Energy Storage Mater. 2021;42:636-644.[DOI]
-
91. Yang B, Zhang X, Ji J, Jiang M, Zhao Y. A comprehensive review of phase change material-based wearable devices for personal thermal management: Mechanism, location and application functionality. Appl Therm Eng. 2024;257:124416.[DOI]
-
92. Zhang Q, Mao Y, Zhang X, Song J, Zhang Z, Wu X. Double-crosslinked phase change hydrogel with superior electro-thermal conversion efficiency and piezoresistive properties for smart healthcare applications. Chem Eng J. 2026;537:176100.[DOI]
-
93. Zhang H, He Q, Zhang F, Duan Y, Qin M, Feng W. Biomimetic intelligent thermal management materials: From nature-inspired design to machine-learning-driven discovery. Adv Mater. 2025;37(30):2503140.[DOI]
-
94. Wu J, Wang M, Dong L, Zhu C, Shi J, Morikawa H. Ultraflexible, breathable, and form-stable phase change fibrous membranes by green electrospinning for personal thermal management. ACS Sustainable Chem Eng. 2022;10(24):7873-7882.[DOI]
-
95. Chen Y, Yu H, Feng Y, Feng W. Custom-assembled phase change modular devices for personalize speciality: Carbon energy thermal management application. Nano Res. 2025;18(3):94907202.[DOI]
-
96. Liu L, Zhang Y, Wu Y, Zhang S, Tang B. Flexible phase change film with motion sensing and tactile recognition for wearable thermal management. Chem Eng J. 2024;494:153271.[DOI]
-
97. Wang S, Ge J, Yang X, Yu Y, He Q, Liao X, et al. Bioinspired swelling-deswelling strategy unlocks synergistic molecular solar thermal-fabric systems for personal thermal management. Adv Mater. 2026;38(12):e14043.[DOI]
-
98. Xie B, Wu H. Material design and integrating strategies for thermoregulatory e-skins with heating and cooling functions. Device. 2024;2(12):100640.[DOI]
-
99. Luo T, Kong L, Lu J, Xie M, Lin B, Fu L, et al. Neuron-inspired flexible phase change materials for ambient energy harvesting and respiration monitoring. Adv Mater. 2024;36(50):2411820.[DOI]
-
100. Jung Y, Ha I, Kim M, Ahn J, Lee J, Ko SH. High heat storing and thermally diffusive artificial skin for wearable thermal management. Nano Energy. 2023;105:107979.[DOI]
-
101. Shi Y, Ji J, Yin Y, Li Y, Xing Y. Analytical transient phase change heat transfer model of wearable electronics with a thermal protection substrate. Appl Math Mech Engl Ed. 2020;41(11):1599-1610.[DOI]
-
103. Zong N, Li S, Zhang Z, Qin M, Feng W. Photothermal energy conversion mechanisms and materials from a cross-scale bonding interactions perspective. Mater Today. 2026;97:103339.[DOI]
-
104. Zhang S, Liu Z, Zhang W, Zhao B, Wu Z, Mu E, et al. Multi-bioinspired flexible thermal emitters for all-day radiative cooling and wearable self-powered thermoelectric generation. Nano Energy. 2024;123:109393.[DOI]
-
106. Zheng X, Dai X, Ge J, Yang X, Yang P, Feng Y, et al. Self-regulating heating and self-powered flexible fiber fabrics at low temperature. J Mater Sci Technol. 2025;220:104-114.[DOI]
-
108. Das A, Apu MMH, Akter A, Al Reza MM, Mia R. An overview of phase change materials, their production, and applications in textiles. Results Eng. 2025;25:103603.[DOI]
-
110. Han X, Yang X, Sun Z, Du M, Du Y, Zhang T, et al. A general design framework of flexible thermoelectric devices bridging power requirements for wearable electronics. Mater Today Phys. 2024;46:101530.[DOI]
-
111. Zhang S, Liu Z, Wu Z, Yao Z, Zhang W, Zhang Y, et al. Boosting self-powered wearable thermoelectric generator with solar absorber and radiative cooler. Nano Energy. 2024;132:110381.[DOI]
-
113. Rashidi S. Applications of machine learning techniques in energy systems integrated with phase change materials-a concise review. Eng Anal Bound Elem. 2023;150:237-245.[DOI]
-
114. Liu S, Han J, Shen Y, Khan SY, Ji W, Jin H, et al. The contribution of artificial intelligence to phase change materials in thermal energy storage: From prediction to optimization. Renew Energy. 2025;238:121973.[DOI]
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