Engineering junction contact states for selective Joule sintering and current distribution control in flexible silver nanowire electrodes
-
Silver nanowire (AgNW) networks are promising electrode candidates for flexible organic solar cells (FOSCs) due to their outstanding optoelectronic properties and mechanical flexibility. However, their practical deployment remains hindered by high ...
MoreSilver nanowire (AgNW) networks are promising electrode candidates for flexible organic solar cells (FOSCs) due to their outstanding optoelectronic properties and mechanical flexibility. However, their practical deployment remains hindered by high junction resistance and inherent surface irregularities, which lead to non-uniform current distribution and increased energy dissipation. Here, we report a hyaluronic acid (HA)-assisted Joule-heating strategy that enables spatially uniform yet junction-selective sintering within AgNWs. The HA treatment increases the density of effective inter-nanowire contacts and improves interfacial adhesion, thereby preconditioning the network for a more homogeneous current distribution. As a result, Joule heating is preferentially localized at electrically active junctions, leading to efficient welding without damaging the overall network. This synergistic regulation produces AgNW electrodes with reduced sheet resistance, improved surface smoothness, and enhanced mechanical robustness, while preserving high optical transparency. Based on the transition from localized current crowding to a homogenized transport regime, which contributes to reduced resistive losses and suppressed recombination, the FOSCs achieve a power conversion efficiency increased from 16.85% to 18.09%, which is the highest reported value of inverted FOSCs. This work establishes a general strategy for coupling network densification with electrically driven selective sintering, offering a scalable route toward high-performance transparent electrodes for next-generation flexible optoelectronics.
Less -
Mahar Sheeraz Khan, ... Jian-Xin Tang
-
DOI: https://doi.org/10.70401/smd.2026.0036 - June 26, 2026







