Rare-earth-doped upconversion nanocrystals (UCNCs), with unique anti-Stokes emission, have been extensively explored, while their performances are hindered by the restriction of parity-forbidden 4f-4f transitions, making their emission ...
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Rare-earth-doped upconversion nanocrystals (UCNCs), with unique anti-Stokes emission, have been extensively explored, while their performances are hindered by the restriction of parity-forbidden 4f-4f transitions, making their emission difficult to control and resulting in low quantum yields. Current research primarily relies on modifying dopant types and concentrations, matrix composition, particle size, core-shell structures, and surface functional groups, to tune the absorption and emission transitions of 4f electrons. While these methods can effectively adjust emission spectra, reduce defects, and enhance luminescence efficiency, they cannot fundamentally regulate the 4f electron transition process, especially with respect to studying the intrinsic luminescence kinetics of rare earth ions. Therefore, a fundamental understanding of the transition behavior of 4f electrons and the ability to intrinsically control their absorption and emission processes are crucial. By manipulating the local optical field around UCNCs, micro-nano structures offer a powerful means to control their upconversion luminescence, making them an important tool for developing efficient optoelectronic devices for display, lighting, and conversion applications. In this review, we comprehensively expound on the optical engineering for UC luminescence control through micro/nano-optical structures. By utilizing structures such as plasmonic antennas, dielectric superstructures, high Q microcavities, and programmable wavefront shapers, precise control over the interaction between light and matter is achieved at multiple spatial scales. Moreover, we systematically analyze how such structures enhance local excitation fields, amplify spontaneous emission, and direct photon extraction, thereby transcending the inherent limitations of rare-earth emitters. By bridging advances in materials chemistry with nanophotonics design principles, this approach unlocks unprecedented control over UC efficiency, spectral purity, and polarization properties.
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Yanan Ji, ... Bin Dong