Supercapacitors, renowned for their high-power density, rapid charge/discharge capabilities, and exceptional cycling stability, have emerged as promising solutions for sustainable and efficient energy storage. Among various electrode materials, carbon materials stands out due to its abundance, excellent electrical conductivity, chemical stability and structural versatility. This review explores the design strategies, performance optimization, and the expanding applications of carbon-based electrodes for supercapacitors. We first analyze the key factors that impact the performance of carbon electrodes for supercapacitors, including pore structure, surface chemistry, electrical conductivity and nanoscale architecture. Subsequently, we provide an in-depth analysis of recent advancements in the rational design of carbon materials, focusing on strategies for optimizing pore architecture, functionalizing surfaces, enhancing conductivity and designing nanostructures. By addressing performance limitations, the review highlights strategies that have significantly improved the efficiency of carbon electrodes. Furthermore, we explore the practical applications of carbon-based supercapacitors in wearable electronics, self-powered devices, and implantable systems. Lastly, we discuss the challenges and opportunities associated by carbon-based electrodes from the perspective of electrode design and practical application.